CobaltMaghrebV1, France, Analysis, bibRecord, 000306

Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Identifieur interne : 000306 ( France/Analysis ); précédent : 000305; suivant : 000307

Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Auteurs : S. Abid [Tunisie] ; M. Rzaigui [Tunisie] ; M. Bagieu-Beucher [France]

Source :

Materials research bulletin [ 0025-5408 ] ; 2000.

RBID : Pascal:01-0328109

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Préparation chimique, Diffraction RX, Structure cristalline, Cadmium phosphate, Cobalt phosphate, Zinc phosphate, Cuivre phosphate, Cation organique, Composé benzénique, Spectre IR, TGA, 6166F, 6166H, Ammonium(p-tolyl), Cyclohexaphosphate.

English descriptors

KwdEn :
- Benzenic compound, Cadmium phosphates, Chemical preparation, Cobalt phosphates, Copper phosphates, Crystal structure, Experimental study, Infrared spectra, Organic cation, TGA, XRD, Zinc phosphates.

Abstract

Four new cyclohexaphosphates with the general formula M(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH₃C₆H₄NH₃)₄P₆O₁₈.8H₂O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å³, and D_x = 1.618 g.cm^-3. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P₆O₁₈^6- ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.

Affiliations:

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to stream Main, to step Exploration: 000D34
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Pascal:01-0328109

Le document en format XML

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C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M = Cd, Co, Zn, and Cu)</title>
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C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M = Cd, Co, Zn, and Cu)</title>
<author><name sortKey="Abid, S" sort="Abid, S" uniqKey="Abid S" first="S." last="Abid">S. Abid</name>
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<author><name sortKey="Rzaigui, M" sort="Rzaigui, M" uniqKey="Rzaigui M" first="M." last="Rzaigui">M. Rzaigui</name>
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<author><name sortKey="Bagieu Beucher, M" sort="Bagieu Beucher, M" uniqKey="Bagieu Beucher M" first="M." last="Bagieu-Beucher">M. Bagieu-Beucher</name>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Benzenic compound</term>
<term>Cadmium phosphates</term>
<term>Chemical preparation</term>
<term>Cobalt phosphates</term>
<term>Copper phosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Infrared spectra</term>
<term>Organic cation</term>
<term>TGA</term>
<term>XRD</term>
<term>Zinc phosphates</term>
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<term>Préparation chimique</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Cadmium phosphate</term>
<term>Cobalt phosphate</term>
<term>Zinc phosphate</term>
<term>Cuivre phosphate</term>
<term>Cation organique</term>
<term>Composé benzénique</term>
<term>Spectre IR</term>
<term>TGA</term>
<term>6166F</term>
<term>6166H</term>
<term>Ammonium(p-tolyl)</term>
<term>Cyclohexaphosphate</term>
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<front><div type="abstract" xml:lang="en">Four new cyclohexaphosphates with the general formula M(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O (M: Cd, Co, Zn, and Cu) are reported. They crystallize with triclinic unit cells and are isotopic. As an example, we give the parameters of Cd(p-CH<sub>3</sub>
C<sub>6</sub>
H<sub>4</sub>
NH<sub>3</sub>
)<sub>4</sub>
P<sub>6</sub>
O<sub>18</sub>
.8H<sub>2</sub>
O: a = 13.834(2), b = 9.974(2), c = 9.134(1) Å, α = 108.12(1), β=91.93(1), γ = 93.45(1)°, Z = 1, P========Imacr;, V = 1193.9(6) Å<sup>3</sup>
, and D<sub>x</sub>
 = 1.618 g.cm<sup>-3</sup>
. The crystal structure was determined using 5214 independent reflections with a final R = 0.027. The atomic arrangement can be described as layers built up by P<sub>6</sub>
O<sub>18</sub>
<sup>6-</sup>
 ring anions, Cd cations, and water molecules, parallel to the (100) planes. Organic cations are located between these layers.</div>
</front>
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<settlement><li>Grenoble</li>
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<name sortKey="Rzaigui, M" sort="Rzaigui, M" uniqKey="Rzaigui M" first="M." last="Rzaigui">M. Rzaigui</name>
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<country name="France"><region name="Auvergne-Rhône-Alpes"><name sortKey="Bagieu Beucher, M" sort="Bagieu Beucher, M" uniqKey="Bagieu Beucher M" first="M." last="Bagieu-Beucher">M. Bagieu-Beucher</name>
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Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Preparation and structure of a series of cyclohexaphosphates : M(p-CH3C6H4NH3)4P6O18.8H2O (M = Cd, Co, Zn, and Cu)

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri